INVESTIGADORES
VILLAR Marcelo Armando
congresos y reuniones científicas
Título:
Well-Defined Synthesis of Poly(dimethylsiloxane) Homopolymers
Autor/es:
M.D. NINAGO; A.J. SATTI; J.A. RESSIA; A.E. CIOLINO; E.M. VALLÉS; M.A. VILLAR
Lugar:
Roma, Italia
Reunión:
Conferencia; 9th International Conference on Chemical and Process Engineering, IcheaP-9; 2009
Institución organizadora:
AIDIC
Resumen:
In this work we present results on the controlled anionic ring-opening polymerization (AROP) of hexamethyl(cyclotrisiloxane) monomer (D3) using sec-butyl lithium as initiator (sec-Bu-Li+), and classical anionic polymerization techniques in whole vacuum-sealed glass reactors. We explored different temperatures and reaction times in order to understand the influence of secondary reactions in order to obtain model poly(dimethylsiloxane) homopolymers (PDMS) with molar masses ranging from 103-105 g/mol, and polydispersity indexes less than 1.1.
