INVESTIGADORES
VILLAR Marcelo Armando
artículos
Título:
Anionic Ring Opening Polymerization of ϵ-Caprolactone Initiated by Lithium Silanolates
Autor/es:
SATTI, ANGEL J.; DE FREITAS, AUGUSTO G. O.; MARANI, M. LORETA SENA; VILLAR, MARCELO A.; VALLÉS, ENRIQUE M.; GIACOMELLI, CRISTIANO; CIOLINO, ANDRÉS E.
Revista:
AUSTRALIAN JOURNAL OF CHEMISTRY
Editorial:
CSIRO PUBLISHING
Referencias:
Año: 2017 vol. 70 p. 106 - 112
ISSN:
0004-9425
Resumen:
Ring-opening homo- and co-polymerization reactions of ϵ-caprolactone were performed by employing anionic polymerization (high vacuum techniques) and lithium silanolates (LS) as initiators. LS were obtained by reaction between hexamethyl(cyclotrisiloxane) and sec-Bu-Li+, or from living poly(dimethylsiloxanyl)lithium chains. The results indicated that LS are efficient initiators for the ring-opening polymerization of ϵ-caprolactone, providing the respective homogeneous polymers in good yields.
