INVESTIGADORES
VILLAR Marcelo Armando
artículos
Título:
Anionic Ring Opening Polymerization of e-Caprolactone Initiated by Lithium Silanolates
Autor/es:
A.J. SATTI; A.G.O. DE FREITAS; M.L. SENA MARANI; M.A. VILLAR; E.M. VALLÉS; C. GIACOMELLI; A.E. CIOLINO
Revista:
AUSTRALIAN JOURNAL OF CHEMISTRY
Editorial:
CSIRO PUBLISHING
Referencias:
Lugar: Collingwood; Año: 2016
ISSN:
0004-9425
Resumen:
Ring-opening homo- and co-polymerization reactions of e-caprolactone were performed by employing anionic polymerization (high vacuum techniques) and lithium silanolates (LS) as initiators. LS were obtained by reaction between hexamethyl(cyclotrisiloxane) and sec-Bu-Li+, or from living poly(dimethyl siloxanyl) lithium chains. The results indicated that LS are efficient initiators for the ring-opening polymerization of e-caprolactone, providing the respective homogeneous polymers in good yields.
