Crystallization behavior of random ethylene–butane copolymers modified with organic peroxide

CLAUDIO J. PÉREZ; VERA A. ALVAREZ; MARCELO D. FAILLA

THERMOCHIMICA ACTA

ELSEVIER SCIENCE BV

Año: 2012 vol. 28 p. 15 - 22

0040-6031

The effect of molecular cross-linking on the crystallization of random ethylene-1-butene copolymers obtained from hydrogenation of model polybutadiene was studied by means of Differential Scanning Calorimetry. The copolymers were modified with different concentrations of organic peroxide in the molten state to generate different crosslinks level. Under isothermal conditions, the crystallization rate of the modified polymers decreased with the average molecular weight likewise to that observed in the unmodified copolymers. Original and modified polymers shows similar isothermal crystallization rate when compared to equivalent weight average molecular weights. Under no isothermal crystallization conditions, the temperature and enthalpy of crystallization of the modified polymer decreased almost linearly with the concentration of peroxide. The activation energy for crystallization increases with the concentration of peroxide indicating that the increment in molecular crosslinking  restricts the crystallization process