INVESTIGADORES
CANEIRO Alberto
artículos
Título:
On the role of carbon in the carbochlorination of refractory oxides
Autor/es:
D. PASQUEVICH; J. ANDRADE GAMBOA; A. CANEIRO
Revista:
THERMOCHIMICA ACTA
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 1992 vol. 209 p. 209 - 222
ISSN:
0040-6031
Resumen:
The two
reaction stages of the carbochlorination of ZrO2 that we have
recently reported were investigated by thermogravimetric measurements and
characterized by following the morphological evolution of the solids by
scanning electronic microscopy (SEM).
Chlorine atoms are proposed as reaction
intermediates in both reaction stages. Evidence of a catalytic-like action of
carbon by the dissociation of chlorine gas is observed in the initial stage,
and the occurrence of the O2-C reaction is inferred in the second
stage.
