CONTRATADOS
CALVO Rafael
artículos
Título:
Synthesis and structure of the dimeric copper(II) complex tetrakis[N-thiazol-2-yl-(4-methylphenyl)sulfonamidate]dicopper(II)
Autor/es:
CABALEIRO, S.; CALVO, R.; CASTRO, J.; GARCIA-VAZQUEZ, J. A.; NAPOLITANO, L. M. B.; NASCIMENTO, O. R.; PEREZ-LOURIDO, P.; ROMERO, J.; SOUSA, A.
Revista:
Journal of Chemical Crystallography
Editorial:
Springer
Referencias:
Año: 2008 vol. 38 p. 71 - 71
ISSN:
1074-1542
Resumen:
The coordination chemistry of the ligand N-thiazol-2-yl-toluenesulfonamidate towards the copper(II) ion has been investigated using an electrochemical synthesis method. The X-ray structure of this complex was elucidated and is discussed. The compound crystallised in the monoclinic crystal system, P21/c space group with a = 17.3888(9), b = 16.3003(9), c = 18.3679(9) Angstrom and  beta = 114.364(1) degrees. Four bidentate sulfathiazolato anions bridge two metal centers in a  paddle-wheel fashion, with the nitrogen atoms as donors to give a dimeric species witha Cu-Cu distance of 2.7859(5) Angstrom .