Electrical, Photoelectrical and Morphological Properties of ZnO Nanofiber Networks

N.C. VEGA; M. TIRADO; D. COMEDI; A. RODRIGUEZ; T. RODRIGUEZ; G.M. HUGHES; C.R. GROVENOR; F. AUDEBERT

MATERIALS RESEARCH

UNIV FED SAO CARLOS

Lugar: São Paulo; Año: 2013 vol. 16 p. 597 - 602

1516-1439

ZnO nanofibre networks (NFNs) were grown by vapour transport method on Si-based substrates. One type of substrate was SiO2 thermally grown on Si and another consisted of a Si wafer onto which Si nanowires (NWs) had been grown having Au nanoparticles catalysts. The ZnO-NFN morphology was observed by scanning electron microscopy on samples grown at 600ºC and 720ºC substrate temperature, while an focused ion beam was used to study the ZnO NFN/Si NWs/Si and ZnO NFN/SiO2 interfaces. Photoluminescence, electrical conductance and photoconductance of ZnO-NFN was studied for the sample grown on SiO2. The photoluminescence spectra show strong peaks due to exciton recombination and lattice defects. The ZnO-NFN present quasi-persistent photoconductivity effects and ohmic I-V characteristics which become nonlinear and hysteretic as the applied voltage is increased. The electrical conductance as a function of temperature can be described by a modified three dimensional variable hopping model with nanometer-ranged typical hopping distances.