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We examine the quantum correlations of spin pairs in the ground state of finite XY chains in a transverse field, by evaluating the quantum discord as well as other related entropic measures of quantum correlations. A brief review of the latter, based on generalized entropic forms, is also included. It is shown that parity effects are of crucial importance for describing the behavior of these measures below the critical field. It is also shown that these measures reach full range in the immediate vicinity of the factorizing field, where they become independent of separation and coupling range. Analytical and numerical results for the quantum discord, the geometric discord and other measures in spin chains with nearest neighbor coupling and in fully connected spin arrays are also provided.