INVESTIGADORES
NINAGO mario daniel
congresos y reuniones científicas
Título:
Amphiphilic block copolymers obtained by simultaneous RAFT & ROP polymerizations
Autor/es:
AUGUSTO G.O. DE FREITAS; MURARO, PAULO I.R.; TANIZE BORTOLOTTO; SUELEN TRINDADE; VANESA SCHMIDT; LOPES, LEONARDO Q.S.; MARIO D. NINAGO; ANGEL J. SATTI; ANDRÉS E. CIOLINO; MARCELO A. VILLAR; CRISTIANO C. GIACOMELLI
Lugar:
Mar del Plata
Reunión:
Congreso; XVI SIMPOSIO LATINOAMERICANO DE POLÍMEROS Y XIV CONGRESO IBEROAMERICANO DE POLÍMEROS; 2018
Institución organizadora:
XVI SIMPOSIO LATINOAMERICANO DE POLÍMEROS Y XIV CONGRESO IBEROAMERICANO DE POLÍMEROS
Resumen:
A completely metal free route to obtain poly(acrylic acid-b-caprolactone) copolymers P(AA-b-CL) by an one-pot method through simultaneous ReversibleAddition-Fragmentation Chain Transfer (RAFT) and Ring Opening Polymerization (ROP) process is reported. The strategy employs a dual initiator that acts as chaintransfer agent (CTA) in the acrylic acid (AA) RAFT polymerization process, and as co-initiator of caprolactone (CL) ring-opening polymerization(ROP).
