INVESTIGADORES
ALFANO Orlando Mario
artículos
Título:
Air Pollution Remediation in a Fixed Bed Photocatalytic Reactor Coated with TiO2
Autor/es:
ESTERKIN, C.R.; NEGRO, A.C.; ALFANO, O.M.; CASSANO, A.E.
Revista:
AICHE JOURNAL
Editorial:
John Wiley & Sons
Referencias:
Año: 2005 vol. 51 p. 2298 - 2310
ISSN:
0001-1541
Resumen:
In a previous paper, the modeling and experimental verification of the radiation field inside a reactor made of several TiO2 coated, parallel, flat glass fiber meshes, bilaterally UV irradiated was accomplished (Esterkin et al., 2002). In this work, the degradation of trichloroethylene (TCE) in an air stream is studied using different values of the pollutant feed concentration, relative humidity and light intensity under operating conditions where kinetic control of the process is established. A kinetic model based on a reaction scheme that involves atomic chlorine as an active reaction intermediate is developed for describing concentration dependencies. It includes, explicitly, the effect of the absorbed light intensity on the rate. The interaction of the existing radiation field with the solid semiconductor to generate electrons and holes in the reaction catalyst activation step is also modeled. All kinetic parameters are estimated from experiments. The obtained kinetic expression gives a first order dependence with respect to the TCE concentration and accounts for a competitive effect of water vapor and TCE for the catalyst active sites. An additional important feature of the derived expression is its ability to represent both limiting cases concerning the dependence of the reaction rate with the irradiation rate; i.e. order 1 or order 0.5 as well as all possible intermediate values. In fact, the equivalent dependence obtained in this work was 0.6, a value closer to the second case. The results show good agreement between predictions derived from the proposed kinetic expression and TCE experimental concentration data at the reactor?s exit. The proposed reactor design provides a practical device for the treatment of contaminated air; it permits a fairly uniform irradiation of the catalytic meshes and a good ratio of the irradiated surface area with respect to the volume of the gaseous reacting mixture. With these features, rather high TCE conversions can be obtained.