INVESTIGADORES
MAESTRI Damian Modesto
artículos
Título:
Phosphatidylcholine/vegetable oil pseudobinary mixtures at the air-water interface. Predictive formulation of oil blends with selected surface behavior
Autor/es:
BENJAMÍN CARUSO; MARÍA PERILLO; DAMIÁN MAESTRI
Revista:
COLLOIDS AND SURFACES B-BIOINTERFACES
Editorial:
Elsevier
Referencias:
Año: 2010 vol. 75 p. 57 - 66
ISSN:
0927-7765
Resumen:
The present work is an attempt to define how to formulate oil blends with an expected surface behavior using easily accessible data such as chemical compositions. Hence, we determined average surface properties of triglycerides (TG) from olive (O), soybean (S), and walnut (W) oils self-organized in Langmuir films alone or in pseudo-binary mixtures with phosphatidylcholines (PC). Collapse pressure (pc), compressibility modulus (K) and molecular area at the closest packing (Amin) were determined from p-mean molecular area (Mma) isotherms. The pc-composition phase diagrams of TG-PC mixtures provided information about oils solubility limit with PCs in the monolayer phase. A thermodynamic equilibrium model was fitted to the line joining points of monolayer-TGliquid phase coexistence and allowed to obtain interaction parameters, w,  which consistently with those of excess surface energy (DGex) and Mma deviations from ideality, contributed to describe interfacial inter-molecular interactions. Oil molar fractions (xTG) for TGs-PCs self-assembling into vesicles were estimated from xTG values at pc@30 mN/m (equilibrium p of bilayers), which resulted higher in egg PC (0.15, 0.2, 0.15 for O, S and W, respectively) than in dipalmitoyl-PC (0.125, 0.075, 0.1). Principal component analysis performed on surface parameters, grouped S and W separated from O. This result was mainly influenced by variables estimating the effect of unsaturation degrees of fatty acids sterified at TGs, Amin and pc. Peanut oils surface data interpolated in pc-C16/C18 and Amin-DBI correlation lines obtained with O-S mixtures (TGmix) and with TGmix-PC supported C16/C18 ratio and DBI as predictors to formulate oil blends with selected surface behavior.