INVESTIGADORES
SATHICQ Angel Gabriel
artículos
Título:
Novel bifunctional mesoporous catalysts based on preyssler heteropolyacids for green pyrrole derivative synthesis
Autor/es:
PORTILLA-ZÚÑIGA, OMAR; SATHICQ, ÁNGEL; MARTÍNEZ, JOSÉ; ROJAS, HUGO; DE GERONIMO, EDUARDO; LUQUE, RAFAEL; ROMANELLI, GUSTAVO P.
Revista:
Catalysts
Editorial:
MDPI AG
Referencias:
Año: 2018 vol. 8
Resumen:
In this paper, we report the synthesis of Preyssler heteropolyacids supported on mesoporous alumina in order to obtain materials with acid?base properties. A series of pyrrole derivatives were synthesized using a suitable procedure under solvent-free conditions. Using the alumina-supported material, more complex pyrrole derivatives can be obtained through a tandem one-pot process that involves the formation of 2-amino-3-cyano 4-H-chromenes by a multicomponent reaction and their subsequent conversion to pyrrole using a Paal?Knorr reaction.