Novel bimetallic magnetic nanocomposites obtained from waste-sourced bio-based substances as sustainable photocatalysts.

APARICIO, FRANCISCA; MIZRAHI, MARTÍN; RAMALLO-LÓPEZ, JOSÉ M.; LAURENTI, ENZO; MAGNACCA, GIULIANA; CARLOS, LUCIANO; MÁRTIRE, DANIEL O.

MATERIALS RESEARCH BULLETIN

PERGAMON-ELSEVIER SCIENCE LTD

Año: 2022 vol. 152

0025-5408

Magnetic Fe-Cu nanocomposites with photocatalytic properties were prepared via the precursor method under different conditions using bio-based substances isolated from urban waste (BBS) as carbon sources. The effects of the amount of organic matter, the target temperature of the pyrolysis treatment (400?800 ◦C), and the replacement of Cu2+ with Ni2+ and Co2+ on the structure, morphology, and photocatalytic capacity of the nanocomposites were analyzed. The capacity of the nanocomposites for the generation of hydroxyl radical under simulated solar irradiation was evaluated via EPR experiments. Carbamazepine (CBZ) photodegradation assays showed an increase of the photocatalytic effciency of the nanomaterials with decreasing amount of BBS and increasing temperature of the pyrolysis treatment employed in the synthesis. Fe-Cu samples pyrolyzed at 600 and 800 ◦C showed a CBZ degradation larger than 70% after 4 h at pH 3 and 5. Lower photocatalytic effciencies were obtained for the Fe-Ni and Fe-Co nanocomposites