INVESTIGADORES
HERRERA Santiago Esteban
artículos
Título:
Gaussian Distribution of Electron Transfer Distance in Redox Terminated Self-Assembled Thiol Monolayers
Autor/es:
DAVIA, FEDERICO G.; HERRERA, SANTIAGO E.; CALVO, ERNESTO JULIO
Revista:
JOURNAL OF PHYSICAL CHEMISTRY C
Editorial:
AMER CHEMICAL SOC
Referencias:
Año: 2019
ISSN:
1932-7447
Resumen:
A Gaussian distribution of tunneling distances due to different orientation populations in electrochemically active self-assembled monolayers composed of alkanethiols of different length has been assumed in a model which leads to a Gaussian distribution of the logarithm of the electron transfer constants. The model has been validated with experimental data for osmium terminated SAMs of different length using a modification of Creager?s method.