INVESTIGADORES
CABRERIZO Franco Martin
artículos
Título:
1H-NMR characterization of the intermediate formed upon UV-A excitation of biopterin, neopterin and 6-hydroxymethylpterin in O2-free aqueous solutions
Autor/es:
MARIANA VIGNONI; M. LAURA SALUM; ROSA ERRA-BALSELLS; ANDRÉS H. THOMAS*; FRANCO M. CABRERIZO *
Revista:
CHEMICAL PHYSICS LETTERS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Año: 2010 vol. 484 p. 330 - 332
ISSN:
0009-2614
Resumen:
Pterins belong to a family of heterocyclic compounds present in a wide range of living systems and participate in relevant biological functions. Under anaerobic conditions,the unstable red intermediate generated by UV-A irradiation of biopterin, neopterin and 6-hydroxymethylpterin was identified by 1H-NMR analysis, in alkaline D2O solutions, as 5,8-dihydro-6-formylpterin.