Chemical and photochemical properties of chloroharmine derivatives in aqueous solutions.

FEDERICO A. O. RASSE-SURIANI #; M. PAULA DENOFRIO #; JUAN G. YAÑUK; M. MICAELA GONZALEZ; EZEQUIEL WOLCAN; MARCO SEIFERMANN; ROSA ERRA-BALSELLS; FRANCO M. CABRERIZO

PHYSICAL CHEMISTRY CHEMICAL PHYSICS

ROYAL SOC CHEMISTRY

Lugar: CAMBRIDGE; Año: 2016 vol. 18 p. 886 - 900

1463-9076

#  These authors contributed equally              ABSTRACT/>Thermal and photochemical stability (fiR),room temperature UV-vis absorption and fluorescence spectra, fluorescence quantum yields (fiF) and lifetimes (tauF), quantum yields of hydrogen peroxide (fiH2O2) and singlet oxygen (fidelta) production, and triplet lifetimes (tauT) have been obtained for the neutral and protonated forms of 6-chloroharmine, 8-chloroharmine and 6,8-dichloroharmine, in aqueous media. When it was possible,the effect of pH and oxygen concentration was evaluated. The nature of electronic transitions of protonated and neutral species of the three investigated chloroharmines were established by TD-DFT calculations. The impact of all the foregoing observations on the biological role of the studied compounds is discussed.