IITEMA   27339
INSTITUTO DE INVESTIGACIONES EN TECNOLOGIAS ENERGETICAS Y MATERIALES AVANZADOS
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
In Situ Characterization of Nanostructured Electrode Materials for Energy Conversion and Storage, Using Probe Beam Deflection Techniques
Autor/es:
MARIANO M. BRUNO; GUSTAVO N. COTELLA; RUSBEL CONEO RODRIGUEZ; DIEGO F. ACEVEDO; C. A. BARBERO; JUAN BALACH
Reunión:
Conferencia; ECS Electrochemical Conference on Energy and the Environment (ECEE 2019): Bioelectrochemistry and Energy Storage; 2019
Resumen:
Nanostructured conductive materials of large surface area which are important in many areas of energy conversion and storage, including supercapacitors and fuel cells. While electrochemical techniques (e.g. cyclic voltammetry) assess the charge transfer processes at the electrode interface, the ion exchange process could only be inferred. Techniques of ion exchange determination, such as the electrochemical quartz crystal microbalance (EQCM) are of difficult application to porous electrodes since it requires fixing the porous material to the oscillating crystal.On the other hand, the techniques that monitor ion fluxes outside the electrode surface are able to study the actual ion exchange between a porous electrode and the electrolyte. Among them, Probe Beam Deflection (PBD) is a technique highly suitable to study porous electrodes.[1] The method uses a laser beam travelling parallel to the electrode surface which is refracted by the refractive index gradient associated with the flux of soluble species perpendicular to the electrode, at the center of the laser beam. Since the detection of beam position is optoelectronic, fast (ms) signals can be measured, unlike EQCM, allowing detecting transient phenomena. Since the flux is directly proportional to the surface area (like the current) the ratio of surface area to geometric pathlength (width of the electrode) assures large signal for porous electrodes.In this report, the study of different electrode materials using Probe Beam Deflection techniques is described. After a qualitative exploration using cyclic deflectometry, a continuous mass transport model is used to quantitatively evaluate the chronodeflectometric response.[2]First, the study of different porous glassy carbon materials is described. Then, PBD is applied to study mesoporous ordered Pt materials active in direct methanol fuel cells.[3] Finally, thin films of mesoporous oxides decorated with Au nanoparticles,[4] are investigated.The potential of minimum charge (PMC) can be determined and compared with the value measured by AC Impedance. Besides, transient phenomena like pH changes or effects on the coupled chemical reactions inside the pores can be easily detected. Therefore, a better understanding on the mass transfer in porous electrodes is obtained.References1. G.G. Láng and C.A. Barbero, Laser Techniques for the Study of Electrode Processes, Springer, Berlin (2012)2. G.A. Planes et al, Chem. Commun., 2146-2148, 20053. G. Garcia, et al, PCCP, 10, 6677-85, 20084. R. Coneo Rodriguez, et al., Sens. & Act. B-Chem., 603 ? 612, 2018