CIDMEJU 26524
CENTRO DE INVESTIGACION Y DESARROLLO EN MATERIALES AVANZADOS Y ALMACENAMIENTO DE ENERGIA DE JUJUY
Unidad Interjuridiccional
artículos
Título:
EQCM and RDE/RRDE Study of Soluble Iron Phthalocyanine Bifunctional Catalyst for the Lithium-Oxygen Battery
Autor/es:
DAVIA, F.; CALVO, ERNESTO J.; R. TORRES W.R.; TESIO A.Y.; MARIA DEL POZO VAZQUEZ
Revista:
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Editorial:
ELECTROCHEMICAL SOC INC
Referencias:
Año: 2017 vol. 164 p. 3785 - 3792
ISSN:
0013-4651
Resumen:
Soluble iron phtalocyanine (FePc) has been studied as a bifunctional catalyst for the oxygen reduction reaction (ORR) and oxygenevolution (OER) in lithium air cathodes by means of electrogravimetry with shear wave dissipation, cyclic voltammetry (CV) androtating ring disk electrode (RRDE). The oxygen reduction reaction (ORR) has been studied on Au in oxygen saturated TBA-PF6in DMSO and LiTFSI-DMSO electrolyte for increasing concentration of Fe-phtalocyanine as redox mediator for the two-electronORR at 2.2 V and the oxidation of the surface Li2O2 product below 3.6 V vs. Li/Li+ where the solvent is stable. The soluble FePccatalyst promotes the ORR solution phase mechanism.
