IQUIBA-NEA 25617
INSTITUTO DE QUIMICA BASICA Y APLICADA DEL NORDESTE ARGENTINO
Unidad Ejecutora - UE
artículos
Título:
Direct determination of parameters of activation of the unimolecular reaction of glutaraldehyde diperoxide by gas chromatography
Autor/es:
GALANTE, N.; JORGE, M.J.; JORGE, N.L.; VARELA, N.; JORGE. L.C.; REGUERA, M.B; PROFETA, M.I.; ROMERO, J.M.; GALANTE, N.; JORGE, M.J.; JORGE, N.L.; VARELA, N.; JORGE. L.C.; REGUERA, M.B; PROFETA, M.I.; ROMERO, J.M.
Revista:
International Journal of Chemistry Studies
Editorial:
International Journal of Chemistry Studies
Referencias:
Lugar: India; Año: 2020 vol. 4 p. 52 - 55
ISSN:
2581-348X
Resumen:
Gas phase thermolysis reaction of glutaraldehyde acid diperoxide (3,6-dibutanoic -1,2,4,5-tetroxane,DPAG) was performed in an injection chamber of a gas chromatograph as a constant time thermal flow reactor, has been applied to obtain activation parameters.(ΔH#=13.07 ± 0.7 Kcal mol-1; ΔS#= -40.28 ± 0.4 cal mol-1 K-1; ΔG#=35.07 ± 0.7 Kcal mol-1) in the 453 ? 553 K temperature range.
