INVESTIGADORES
PEREDA Selva
artículos
Título:
Phase behavior modeling of alkyl-amine+water mixtures and prediction of alkane solubilities in alkanolamine aqueous solutions with GCA-EoS
Autor/es:
F. A. SANCHEZ; T. M. SORIA; S. PEREDA; A.H. MOHAMMADI; D. RICHON; E.A. BRIGNOLE
Revista:
INDUSTRIAL & ENGINEERING CHEMICAL RESEARCH
Editorial:
AMER CHEMICAL SOC
Referencias:
Año: 2010 vol. 49 p. 7085 - 7092
ISSN:
0888-5885
Resumen:
Precise knowledge of phase behavior of natural gas + aqueous alkanolamine solutions is of interest to design and optimize amine absorption units. In this work, we extend a group contribution with association equation of state to the modeling of phase behavior of mixtures containing water, alkanolamine, and light hydrocarbons (HC). The model parameters were estimated on the basis of binary vapor-liquid equilibrium and liquid-liquid equilibrium data of the following binary systems: HC + amines, HC + alcohol, water + amine, water + alcohol. The group contribution approach allows the use of an extended databank of experimental data which gives a solid foundation for predicting hydrocarbon solubility in aqueous alkanolamine solutions.