X-ray absorption study of the Fe and Mo valence states in Sr2FeMoO6

H. P. MARTINS; F. PRADO; A. CANEIRO; VICENTI F C; CHAVEZ D. S.; MOSSANEK R. J. O.; ABBATE M

JOURNAL OF ALLOYS AND COMPOUNDS

ELSEVIER SCIENCE SA

Lugar: Amsterdam; Año: 2015 vol. 640 p. 511 - 516

0925-8388

We studied the Fe and Mo valence states in Sr2FeMoO6 using X-ray absorption spectroscopy. The experimental results were analyzed using atomic multiplet plus crystal field calculations. The analysis indicates that the Fe ions present a fairly ionic Fe3+ (3d5) valence, and that the Mo ions are in a strongly covalent Mo5+ (4d1) state. The presence of Fe ions in a 2+ valence state can be excluded from the Fe-L2,3 spectrum. These results can be understood taking into account the relative energy of the d-levels,the relative strength of the M d?O p mixing, and the exchange stabilization of the Fe3+ ion.