INQUISUR 21779
INSTITUTO DE QUIMICA DEL SUR
Unidad Ejecutora - UE
artículos
Título:
Bis(dimethylformamide-Û-O)tetrakis{Ý-fenoprofenate(Û2-O,O¡¦)}dicopper(II)
Autor/es:
AGOTEGARAY, MARIELA A.; QUINZANI, OSCAR V.; FACCIO, RICARDO; GOYENOLA, CECILIA; MOMBRÚ, ALVARO W.
Revista:
Acta Crystallographica Section E
Editorial:
International Union of Crystallography
Referencias:
Año: 2008 vol. 64 p. 1612 - 1613
Resumen:
The title compound, [Cu2(C15H13O3)4(C3H7NO)2], is formed
by the chelate coordination of four racemic fenoprofenate
(fenoprofenate is 2,3-phenoxyphenyl propionate) anions and
two dimethylformamide molecules to two copper(II) ions,
building a paddle-wheel dinuclear molecule. The distorted
square-pyramidal coordination of each CuII atom is made up
of four O atoms of the four fenoprofenate units and another O
atom from a dimethylformamide molecule. The two enantiomeric
forms of the fenoprofenate anions are present in the
complex, in an optically inactive centrosymmetric arrangement.
of four O atoms of the four fenoprofenate units and another O
atom from a dimethylformamide molecule. The two enantiomeric
forms of the fenoprofenate anions are present in the
complex, in an optically inactive centrosymmetric arrangement.
by the chelate coordination of four racemic fenoprofenate
(fenoprofenate is 2,3-phenoxyphenyl propionate) anions and
two dimethylformamide molecules to two copper(II) ions,
building a paddle-wheel dinuclear molecule. The distorted
square-pyramidal coordination of each CuII atom is made up
of four O atoms of the four fenoprofenate units and another O
atom from a dimethylformamide molecule. The two enantiomeric
forms of the fenoprofenate anions are present in the
complex, in an optically inactive centrosymmetric arrangement.
of four O atoms of the four fenoprofenate units and another O
atom from a dimethylformamide molecule. The two enantiomeric
forms of the fenoprofenate anions are present in the
complex, in an optically inactive centrosymmetric arrangement.
2(C15H13O3)4(C3H7NO)2], is formed
by the chelate coordination of four racemic fenoprofenate
(fenoprofenate is 2,3-phenoxyphenyl propionate) anions and
two dimethylformamide molecules to two copper(II) ions,
building a paddle-wheel dinuclear molecule. The distorted
square-pyramidal coordination of each CuII atom is made up
of four O atoms of the four fenoprofenate units and another O
atom from a dimethylformamide molecule. The two enantiomeric
forms of the fenoprofenate anions are present in the
complex, in an optically inactive centrosymmetric arrangement.
of four O atoms of the four fenoprofenate units and another O
atom from a dimethylformamide molecule. The two enantiomeric
forms of the fenoprofenate anions are present in the
complex, in an optically inactive centrosymmetric arrangement.
II atom is made up
of four O atoms of the four fenoprofenate units and another O
atom from a dimethylformamide molecule. The two enantiomeric
forms of the fenoprofenate anions are present in the
complex, in an optically inactive centrosymmetric arrangement.
