AUTOMATIC FLOW-BATCH SYSTEM FOR COLD VAPOR ATOMIC ABSORPTION SPECTROSCOPY DETERMINATION OF MERCURY IN HONEY FROM ARGENTINA USING ONLINE SAMPLE TREATMENT.

DOMINGUEZ; GTUNHUT; PISTONESI; DI NEZIO; CENTURION

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY

AMER CHEMICAL SOC

Lugar: Washington; Año: 2012 vol. 60 p. 4812 - 4817

0021-8561

An automatic flow-batch system that includes two borosilicate glass chambers to perform sample digestion and cold vapor atomic absorption spectroscopy determination of mercury in honey samples was designed. The sample digestion was performed by using a low-cost halogen lamp to obtain the optimum temperature. Optimization of the digestion procedure was done using a Box−Behnken experimental design. A linear response was observed from 2.30 to 11.20 μg Hg L−1. The relative standard deviation was 3.20% (n = 11, 6.81 μg Hg L−1), the sample throughput was 4 sample h−1, and the detection limit was 0.68 μg Hg L−1. The obtained results with the flow-batch method are in good agreement with those obtained with the reference method. The flow-batch system is simple, allows the use of both chambers simultaneously, is seen as a promising methodology for achieving green chemistry goals, and is a good proposal to improving the quality control of honey.