Weak ferromagnetism and superparamagnetic clusters coexistence in YFe1−xCoxO3 (0 ≤ x ≤ 1) perovskites

NASSIF, VIVIAN; GUIMPEL, JULIO; POMIRO, FERNANDO; PAESANO, ANDREA; SÁNCHEZ, RODOLFO D.; GIL, DIEGO M.; GÓMEZ, MARÍA I.; CARBONIO, RAÚL E.

MATERIALS RESEARCH BULLETIN

PERGAMON-ELSEVIER SCIENCE LTD

Año: 2017 vol. 94 p. 472 - 482

0025-5408

YFe1-xCoxO3 (x = 0, 0.3, 0.5, 0.7 and 1) perovskite solid solutions were synthesized by thermal decomposition of the cyano-metal complexes Y[Fe1-xCox(CN)6]·4H2O. All perovskites belong to the orthorhombic Pnma space group. Mössbauer spectra at room temperature show that samples with low Co3+ content are magnetically ordered, while samples with high Co3+ content are paramagnetic. A clear decrease of the magnetic order temperature was observed by magnetization vs. temperature experiments. At high temperatures, YFe0.3Co0.7O3 is paramagnetic and a non common increase of magnetization is observed. The later can be related to the thermal excitation of Co3+ in low spin (LS) configuration to intermediate (IS) or high spin (HS) configuration. Along the different compositions of YFe1-xCoxO3 solid solutions there is a competition between weak ferromagnetism (WFM) and superparamagnetic (SPM) clusters. WFM due to Fe3+ cations prevail in rich Fe3+ samples (x = 0 and 0.3) and the Fe3+ cations that form SMP clusters prevail in the sample with x = 0.7. Besides, in the sample with x = 0.5 we postulate a slight prevalence of WFM due to Fe3+ cations. For YFe1-xCoxO3 with x = 0.3, 0.5 and 0.7 neutron powder data at 2, 150 and 350 K were refined with the irreducible representation Γ4 (Ax Fy Gz).