INQUINOA   21218
INSTITUTO DE QUIMICA DEL NOROESTE
Unidad Ejecutora - UE
artículos
Título:
Parameters of viscous flow in dilute solutions of polyalkyl glycol ethers in secondary alcohols
Autor/es:
SILVIA AZNAREZ, M. M. ELSA F. DE RUIZ HOLGADO AND ELEUTERIO L. ARANCIBIA
Revista:
JOURNAL OF MOLECULAR LIQUIDS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2011 vol. 162 p. 1 - 6
ISSN:
0167-7322
Resumen:
Densities and viscosities were measured for the binary dilute mixtures of triethylene glycol monomethyl ether (TRIEGMME) in 2-alcohols (2-propanol (2- PR), 2-butanol (2-BU), and 2-pentanol (2-PE)) and tetraethylene glycol dimethyl ether (TEGDME) in 2-pentanol, at temperatures from 288.15 K to 318.15 K and in 0 ¡Ü x2 ¡Ü0.10 mole fraction range of the polyalkyl glycol ethers. The values of the dynamic viscosity in the TRIEGMME + 2-PR systems are more viscous than pure solvent at the work temperatures. The Jones-Dole B coefficients and G the dynamic viscosity in the TRIEGMME + 2-PR systems are more viscous than pure solvent at the work temperatures. The Jones-Dole B coefficients and G the dynamic viscosity in the TRIEGMME + 2-PR systems are more viscous than pure solvent at the work temperatures. The Jones-Dole B coefficients and G the dynamic viscosity in the TRIEGMME + 2-PR systems are more viscous than pure solvent at the work temperatures. The Jones-Dole B coefficients and G the dynamic viscosity in the TRIEGMME + 2-PR systems are more viscous than pure solvent at the work temperatures. The Jones-Dole B coefficients and G 2 ¡Ü0.10 mole fraction range of the polyalkyl glycol ethers. The values of the dynamic viscosity in the TRIEGMME + 2-PR systems are more viscous than pure solvent at the work temperatures. The Jones-Dole B coefficients and GG interaction parameters for viscous flow values were calculated and explain the behaviour observed. The partial molar volumes at infinite dilution of solute in 2- alkanols were calculated by the parameters of viscous flow obtained in dilute solutions polyalkyl glycol ethers in 2-alkanols. The values have been compared with the values of partial molar volume at infinite dilution obtained by density measurement for both solutes in the 2-propanol, 2-butanol, and 2-pentanol.