INQUINOA 21218
INSTITUTO DE QUIMICA DEL NOROESTE
Unidad Ejecutora - UE
artículos
Título:
Synthesis, spectroscopic characterization and theoretical studies of polypyridine homoleptic Cu (I) complexes
Autor/es:
PEYROT, ANALÍA M.; FAGALDE, FLORENCIA; TOMAS, FEDERICO M.L A.
Revista:
POLYHEDRON
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2021 vol. 202 p. 115203 - 115216
ISSN:
0277-5387
Resumen:
In this work, we focus on the synthesis and physicochemical characterization of four mononuclear copper (I) complexes with π-conjugated ligands substituted by methylgroups of formulae [CuL2]+ with L= dmb , dmp , tmp and phen (dmb= 4,4´-dimethyl-2,2´-bipyridine; dmp =5,6-dimethyl-1,10- phenanthroline ; tmp = 3,4,7,8-tetramethyl-1,10-phenanthroline and phen = 1,10- phenanthroline) . By TD-DFT it would be possible to discuss and rationalize the geometry of the complexes and the origin of metal-to-ligand charge transfer in a square-planar distortion state.
