Chemical and physico-chemical characterization of lignins obtained from the ethanol-water fractionation of bagasse

VALLEJOS M.E.; FELISSIA, FERNANDO; CURVELO A.A.S.; ZAMBON M.; RAMOS L.; AREA, MARIA CRISTINA

BIORESOURCES

NORTH CAROLINA STATE UNIV DEPT WOOD & PAPER SCI

Lugar: Raleigh; Año: 2011 vol. 6 p. 1158 - 1171

1930-2126

Organosolv lignins can replace petroleum chemicals such as phenol either partially or totally in various applications. Eight lignins, seven of which corresponded to the ethanol-water fractionation of bagasse and the other to a reference lignin (Alcell®) were analyzed with the aim to evaluate their chemical and physicochemical characteristics. The purity of the lignin fractions was determined by high pressure liquid chromatography (HPLC) and by ash content. Fourier Transform-Infrared Spectroscopy (FTIR) techniques and differential UV spectroscopy were applied to identify the chemical groups in the lignin samples. The molecular weight distribution was determined by size exclusion chromatography (HPSEC). Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) techniques were used to determine the mass loss due to the high temperature treatment. The lignins studied showed the presence of p-hydroxyphenyl (H unit) and a greater proportion of guaiacyl (G unit) moieties, lower purity, similar orgreater amount of phenolic hydroxyl groups, and higher degradation temperatures, than the Alcell® lignin.