INTEQUI 20941
INSTITUTO DE INVESTIGACIONES EN TECNOLOGIA QUIMICA
Unidad Ejecutora - UE
artículos
Título:
Insight into the metal content-structure-property relationship in lanthanide metal-organic frameworks: optical studies, magnetism and catalytic performance
Autor/es:
G. E. GOMEZ; G: A: SOLER ILLIA; E. V. BRUSAU; G. E. NARDA; J. SACANELL
Revista:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Lugar: Weinheim; Año: 2018 vol. 20 p. 2452 - 2460
ISSN:
1434-1948
Resumen:
Two series of metal?organic frameworks (MOFs) basedon a flexible ligand and trivalent lanthanides were obtainedhydrothermally in order to explore their optical properties at lowtemperatures, magnetism and catalytic activity in relation to theirstructural features. A multisite analysis was performed according tothe 4f-4f transitions. Moreover, the heterogeneous catalytic activityof the series was evaluated in one-pot cyanosilylation withbenzaldehyde as substrate. Recyclability, structure conservation andcatalytic efficiency were also evaluated and compared withanalogous compounds.
