INVESTIGADORES
DELLA VEDOVA Carlos Omar
artículos
Título:
Synthesis, X-ray Structures, and spectroscopic characterization of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2]
Autor/es:
JUNCAL, LUCIANA C.; FERRER, EVELINA G.; WILLIAMS, PATRICIA A.M.; BOESE, ROLAND; POZZI, C. GUSTAVO; DELLA VÉDOVA, CARLOS O.; ROMANO, ROSANA M.
Revista:
CHEMICAL PHYSICS LETTERS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Año: 2022 vol. 794
ISSN:
0009-2614
Resumen:
Single crystals of cis and trans-bis(O-propyldithiocarbonato)bis(pyridine)nickel(II), cis and trans-[Ni(CH3CH2CH2OC(S)S)2(C5H5N)2], have been prepared and studied using single crystal X-ray diffraction method and IR spectroscopy. The crystal structure of tetracoordinated Ni(II) xanthate complex, bis(O-propyldithiocarbonato)nickel(II), [Ni(CH3CH2CH2OC(S)S)2], was also determined and compared with the previously reported structure. The existence of a cis form for a hexacoordinated species of the [NiS4N2] type is infrequent for this family of complexes.
