IFLP 13074
INSTITUTO DE FISICA LA PLATA
Unidad Ejecutora - UE
artículos
Título:
Aryl Naphthoates: A Conformational Analysis Supported by Single-Crystal X-Ray Diffraction
Autor/es:
ECHEVERRIA, GUSTAVO A.; JIOS, JORGE L.; DUDDECK, HELMUT; WARTCHOW, RUDOLF
Revista:
AUSTRALIAN JOURNAL OF CHEMISTRY
Editorial:
CSIRO PUBLISHING
Referencias:
Año: 2016 vol. 69 p. 291 - 299
ISSN:
0004-9425
Resumen:
The conformational study by X-ray diffraction of 12 aroyl esters of ortho-acetyl phenols is reported. The data are supported by theoretical calculations and described in terms of co-planarity, intramolecular steric interference, and intermolecular contacts. The observed hindrance was correlated with the C=O stretching vibration values in infrared spectroscopy.
