IFLP 13074
INSTITUTO DE FISICA LA PLATA
Unidad Ejecutora - UE
artículos
Título:
Copper(II) and zinc(II) complexes with 2-formylpyridine-1 derived hydrazones
Autor/es:
A. A. RECIO DESPAIGNE; J. G. DA SILVA; A. C. M. DO CARMOA; F. SIVES; O. E. PIRO; E. E. CASTELLANO; H. BERALDO
Revista:
POLYHEDRON
Editorial:
Elsevier
Referencias:
Año: 2009
ISSN:
0277-5387
Resumen:
In the present work 2-formylpyridine-para-chloro-phenyl hydrazone (H2FopClPh) and 2-formylpyridine-para-nitro-phenyl hydrazone (H2FopNO2Ph) were obtained, as well as their copper(II) and zinc(II) complexes [Cu(H2FopClPh)Cl2] (1), [Cu(2FopNO2Ph)Cl] (2), [Zn(H2FopClPh)Cl2] (3) and [Zn(H2FopNO2Ph)Cl2] (4). Upon re-crystallization in DMSO:acetone conversion of 2 into [Cu(2FopNO2Ph)Cl(DMSO)] (2a) and of 4 into [Zn(2FopNO2Ph)Cl(DMSO)] (4a) occurred. The crystal structures of 1, 2a, 3 and 4a were determined.
