Magnetic ZnFe2O4 nanoferrites studied by X-ray magnetic circular dichroism and Mössbauer Spectroscopy

S. J. STEWART, S. J. A. FIGUEROA, M. B. STURLA, R. B. SCORZELLI, F. GARCÍA, F. G. REQUEJO

PHYSICA B - CONDENSED MATTER

Elsevier

Año: 2007 vol. 389 p. 155 - 158

0921-4526

ZnFe2O4 nanoparticles (6 nm) were synthesized by hydrothermal methods. Subsequent mechanical treatment applied to the nanocrystalline material caused an increment of the grain size up to 13 nm. The samples were characterized by X-ray absorptionspectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD) at the Fe–K edge and 57Fe Mössbauer spectroscopy. The absorption pre-edge features indicate that Fe3+ ions occupy non-centrosymmetric sites. XAS data evidence the presence of Fe3+ tetrahedrally coordinated while XMCD spectra reflect the magnetic character of the compound The Mössbauer results show a superparamagnetic behaviour with blocking temperatures at 40 and 250K for 6 and 13nm samples, respectively. The 4.2K Mössbauer spectra reflect that Fe3+ ions occupy both octahedral and tetrahedral spinel sites. All these results provide consistent evidence of the highdegree of inversion achieved by these combined methods, which modifies the long-range ordering. We also demonstrated that, starting from a non-equilibrium state, an increment of the inversion activated by the milling occurs in spite of the augment of the grain size.