INQUIMAE   12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Adsorption and reduction of palladiumdimethylglyoxime complex
Autor/es:
RAMÍREZ SILVANA A.; GORDILLO GABRIEL J.
Revista:
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Editorial:
Elsevier
Referencias:
Lugar: Amsterdam; Año: 2009 vol. 629 p. 147 - 151
ISSN:
0022-0728
Resumen:
The voltammetric reduction of PdII(DMGH)2 preadsorbed on mercury in 0.2 M acetic/acetate buffer (pH
4.85) was studied. Two adsorbed surface stages could be distinguished: while a submonolayer is present
molecules adsorb parallel to the electrode, but at high surface concentration perpendicular interactions
between adsorbed molecules lead to bilayer or even multilayer formation. The surface charge value
obtained for the reduction of a virtual monolayer is QM = 38 lC cm2. The electrochemical behaviour of
adsorbed species under submonolayer coverage is explained in terms of an ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
adsorbed species under submonolayer coverage is explained in terms of an ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
4.85) was studied. Two adsorbed surface stages could be distinguished: while a submonolayer is present
molecules adsorb parallel to the electrode, but at high surface concentration perpendicular interactions
between adsorbed molecules lead to bilayer or even multilayer formation. The surface charge value
obtained for the reduction of a virtual monolayer is QM = 38 lC cm2. The electrochemical behaviour of
adsorbed species under submonolayer coverage is explained in terms of an ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
adsorbed species under submonolayer coverage is explained in terms of an ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
II(DMGH)2 preadsorbed on mercury in 0.2 M acetic/acetate buffer (pH
4.85) was studied. Two adsorbed surface stages could be distinguished: while a submonolayer is present
molecules adsorb parallel to the electrode, but at high surface concentration perpendicular interactions
between adsorbed molecules lead to bilayer or even multilayer formation. The surface charge value
obtained for the reduction of a virtual monolayer is QM = 38 lC cm2. The electrochemical behaviour of
adsorbed species under submonolayer coverage is explained in terms of an ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
adsorbed species under submonolayer coverage is explained in terms of an ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
QM = 38 lC cm2. The electrochemical behaviour of
adsorbed species under submonolayer coverage is explained in terms of an ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.
ErCi surface reaction scheme
and a rate expression that takes into account attractive forces between the adsorbed reactant complex
molecules.