INQUIMAE   12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Caged aminoacids for visible light photodelivery
Autor/es:
MARCELO SALIERNO; CECILIA FAMELI; ROBERTO ETCHENIQUE
Revista:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Referencias:
Año: 2008 p. 1125 - 1125
ISSN:
1434-1948
Resumen:
We present a photocleavable protecting group based on ruthenium bipyridyl complexes and suitable for amino acid photodelivery. We discuss the photochemical properties of the caged glutamate, which is a major neurotransmitter in the CNS. The molar absorptivity for the caged glutamate at 450 nm is å = 4200 M–1cm–1 and its quantum yield of photore- lease at 450 nm is ÖPD = 0.035, which is about 17 times higher than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. lease at 450 nm is ÖPD = 0.035, which is about 17 times higher than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. lease at 450 nm is ÖPD = 0.035, which is about 17 times higher than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. lease at 450 nm is ÖPD = 0.035, which is about 17 times higher than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. å = 4200 M–1cm–1 and its quantum yield of photore- lease at 450 nm is ÖPD = 0.035, which is about 17 times higher than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. ÖPD = 0.035, which is about 17 times higher than that of the most active organic caged compound at this wavelength. Similar figures are obtained for other á-amino acids. acids. acids. acids. á-amino acids.