INQUIMAE   12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Caged aminoacids for visible light photodelivery
Autor/es:
MARCELO SALIERNO; CECILIA FAMELI; ROBERTO ETCHENIQUE
Revista:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Referencias:
Año: 2008 p. 1125 - 1128
ISSN:
1434-1948
Resumen:
We present a photocleavable protecting group based on ruthenium
bipyridyl complexes and suitable for amino acid
photodelivery. We discuss the photochemical properties of
the caged glutamate, which is a major neurotransmitter in
the CNS. The molar absorptivity for the caged glutamate at
450 nm is å = 4200 M1cm1 and its quantum yield of photore-
lease at 450 nm is ÖPD = 0.035, which is about 17 times higher
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
lease at 450 nm is ÖPD = 0.035, which is about 17 times higher
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
lease at 450 nm is ÖPD = 0.035, which is about 17 times higher
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
lease at 450 nm is ÖPD = 0.035, which is about 17 times higher
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
å = 4200 M1cm1 and its quantum yield of photore-
lease at 450 nm is ÖPD = 0.035, which is about 17 times higher
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
ÖPD = 0.035, which is about 17 times higher
than that of the most active organic caged compound at this
wavelength. Similar figures are obtained for other á-amino
acids.
acids.
acids.
acids.
á-amino
acids.