INQUIMAE   12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Dendocarbin A, a sesquiterpene lactone from Drimys winteri.
Autor/es:
CRISTIAN PAZ ROBLES; DARIO MERCADO; SEBASTIAN SUAREZ; RICARDO BAGGIO
Revista:
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Editorial:
WILEY-BLACKWELL PUBLISHING, INC
Referencias:
Lugar: Londres; Año: 2014
ISSN:
0108-2701
Resumen:
The natural compound dendocarbin A, C15H22O3, is a sesquiterpene lactone isolated for the first time from Drimys winteri for var chilensis. The compound crystallizes in the orthorhombic space group P212121 and its X-ray crystal structure confirmed the S/R character of the chiral centres at C-5/C-10 and C-9/C-11, respectively. The -OH group at C-11 was found to be involved in intermolecular hydrogen bonding, defining chains along the 21 screw axis.