INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Communication between Remote Moieties in Linear Ru?Ru?Ru Trimetallic Cyanide-Bridged Complexes
Autor/es:
PIESLINGER, G; ALBORES, P.; SLEP, L. D.; COE, B. J.; TIMPSON C. J.; BARALDO, L. M:
Revista:
INORGANIC CHEMISTRY
Editorial:
AMER CHEMICAL SOC
Referencias:
Lugar: Washington; Año: 2013 vol. 52 p. 2906 - 2917
ISSN:
0020-1669
Resumen:
In this article, we report the structural, spectroscopic, and electrochemical properties of the cyanide-bridged complex salts trans-[(NC)RuII(L)4(μ-CN)RuII(py)4Cl]PF6 and trans-[RuII(L)4{(μ-CN)RuII(py)4Cl}2](PF6)2 (L = pyridine or 4-methoxypyridine). The mixed-valence forms of these compounds show a variety of metal-to-metal charge-transfer bands, including one arising from charge transfer between the remote ruthenium units. The latter is more intense when L = 4-methoxypyridine and points to the role of the bridging ruthenium unit in promoting mixing between the dπ orbitals of the terminal fragments.
