INQUIMAE   12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Formation of Coordinated C-Nitroso Compounds by Reaction of K[IrCl5NO] with Alkenes
Autor/es:
N. ESCOLA; A. LLEBARIA; G. LEITUS; F. DOCTOROVICH
Revista:
ORGANOMETALLICS
Editorial:
ACS
Referencias:
Año: 2006 vol. 25 p. 3799 - 3799
ISSN:
0276-7333
Resumen:
Summary: Coordinated C-nitrosochloroalkanes were obtained by electrophilic addition of K[IrCl5NO] to cyclooctene or dicyclopentadiene; in the last case, the crystal structure of trans-[IrCl4(CH3CN)(syn-1-chloro-2-nitroso-1,2-dihydrodicyclopentadiene)] was determined by X-ray diffraction. Although the reaction between NOCl and alkenes is well-known, there are Very few examples of clean electrophilic addition of coordinated NO+ to alkenes.