INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Effects of the nature and charge of the topmost layer in layer by layer
Autor/es:
E.J. CALVO; V. FLEXER; M. TAGLIAZUCCHI; P. SCODELLER
Revista:
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: Cambridge, UK; Año: 2010 vol. 12 p. 10033 - 10039
ISSN:
1463-9076
Resumen:
Organized layer-by-layer nanostructured amperometric enzyme electrodes with self-contained redox polyelectrolyte mediators have shown important effects depending on the nature and charge of the adsorbed topmost layer. Adsorption of PVS causes the drop of the catalytic responses to negligible values due to hindrance in electron hopping and enzyme wiring.
