INQUIMAE   12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Structural and Spectroscopic Evidence of Strong Electronic Delocalization through a Cyanido Bridge in a Mixed-Valence Os–Ru Complex
Autor/es:
MELINA B. ROSSI; KHALIL A. ABBOUD; PABLO ALBORÉS; LUIS M. BARALDO
Revista:
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Editorial:
WILEY-V C H VERLAG GMBH
Referencias:
Año: 2010 p. 5613 - 5613
ISSN:
1434-1948
Resumen:
We report the properties of a trinuclear cyanido-bridged complex, trans-[(dmap)4RuII{(μ-NC)OsIII(CN)5}2]4– [14–; dmap= 4-(dimethylamino)pyridine], whose structure and electronic and vibrational spectra present strong evidence of partial redox states for the three metal ions, an unprecedented feature for cyanido-bridged systems.