INQUIMAE 12526
INSTITUTO DE QUIMICA, FISICA DE LOS MATERIALES, MEDIOAMBIENTE Y ENERGIA
Unidad Ejecutora - UE
artículos
Título:
Rational design of covalently bridged [FeIII2MIIO] clusters
Autor/es:
PABLO ALBORÉS; EVA RENTSCHLER
Revista:
JOURNAL OF THE CHEMICAL SOCIETY, DALTON TRANSACTIONS
Editorial:
Royal Society of Chemistry
Referencias:
Año: 2010 p. 5005 - 5019
ISSN:
0300-9246
Resumen:
We are reporting the synthesis and structural characterization of dimericunits of basic carboxylates bearing the neutral [FeIII2MIIO] motif fordifferent 3d M metals, covalently bound through 2,2¢-bipyrimidine.Their magnetic properties evidence a weak antiferromagnetic interactionthrough the bpym bridge between isolated spin ground states (in someexamples) arising from intra-Fe2MO core exchange couplings.
