IAFE   05512
INSTITUTO DE ASTRONOMIA Y FISICA DEL ESPACIO
Unidad Ejecutora - UE
artículos
Título:
Ground state for two-electron and electron-muon three-body atomic systems
Autor/es:
K.V. RODRIGUEZ, L. U. ANCARANI, G. GASANEO, AND D. M. MITNIK
Revista:
INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY
Referencias:
Año: 2008
ISSN:
0020-7608
Resumen:
In this paper the Angular Correlated Configuration Interaction
method previously introduced by some of the authors is extended
to three-body atomic systems with general masses.
A recently proposed angularly correlated basis set is used
to construct ground state wave functions which:
(i) satisfy exactly Kato cusp conditions at the two-body
coalescence points; (ii) have only linear coe cients;
(iii) show a fast convergency rate for the energy.
The eficiency of the construction is illustrated by the study
of the negatively charged hydrogen-like systems
( H , T , D , 1H and Mu ), neutral helium-like systems
( He+2, 4He+2, 3He+2, He+2, 4He+2 and 3He+2),
and positively charged lithium-like systems
( Li+3, 7Li+3, 6Li+3, Li+3, 7Li+3 and 6Li+3).
The ground state energies and other mean values are
compared with those given in the literature, when available.
Wave functions with a moderate number (20 maximum)
linear coe cients are given explicitly;
they are su ciently simple and su ciently accurate to
be used in practical calculations of atomic collision
in which multi-dimensional integrations are involved.