INFIQC   05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
congresos y reuniones científicas
Título:
Microalgae as a renewable fuel source: Fast pyrolysis of Botryococcus braunii
Autor/es:
ROXANA V. PILONI; INES C. DAGA; R. CARLOS URCELAY; ELIZABETH L. MOYANO
Lugar:
Rio de Janeiro
Reunión:
Simposio; 17th International Symposium on Advancing the Chemical Sciences (ISACS17): Challenges in Chemical Renewable Energy; 2015
Institución organizadora:
Royal Society of Chemistry
Resumen:
The high consumption of fossil fuels, along with the decline in the number of exploited oil fields and an excessive increase in CO2 emissions and other pollutants, have created the need for researching new sources of fuels, which have the property of being renewable and environmentally friendly, and develop new methods for their preparation. In this context, algae emerge as a new source of renewable fuels or bio-fuels, due to numerous advantages offered in relation to the higher vascular plants implemented nowadays, and because algae currently proliferate massively due to the pollution of watercourses. For obtaining biofuel from algal material the fast pyrolysis technique was used, which consisted of thermal degradation of organic matter in the absence of oxygen under vacuum conditions. Botryococcus braunii alga was used as starting material because it contains a high percentage of lipids, which ensures a good production and quality of bio-oils1. Previous characterization of the alga was carried out by elemental and proximate analysis techniques. Fast pyrolysis experiments were conducted in a fixed bed reactor on a laboratory scale. Temperature scan between 300 and 600 °C was performed in order to find the best conditions for mayor bio-oil recovery. For each reaction the amounts of liquid an solid were determined by direct weight, and the gas fraction was calculated by difference of the first two. It was observed that the alga contains over 50% w/w lipids in its composition, which is very beneficial if the goal is to get long-chain hydrocarbons and fatty acids. Also, the protein content is low, and therefore the content of nitrogenated compounds is also low. This is also beneficial because nitrogen compounds are unwanted for a fuel, since the energy efficiency is reduced and in the combustion process generates nitrogen oxides as environmental contaminants. In the elemental analysis study it was observed that B. braunii alga has a high carbon content, which correlates with the high lipid content, and a low percentage of nitrogen which correlated with the low amount of protein. The results of the fast pyrolysis experiments are shown in the next table:Table 1 ? Products yields in the fast pyrolysis of alga B. brauniiTemperature (°C)Yield (%)SolidLiquidGas300343333400649455002603860014851We found that the highest bio-liquid recovered was obtained at 500°C (60% yield). Bio-oil composition was analyzed using the GC-MS technique and there is no great difference between the samples with the change of temperature. The chromatograms showed a high concentration of mono-insaturated long-chain hydrocarbons with traces of oxygenated compounds such as phenol and long chain derivatives (alcohols and carboxylic acids). Thus, the resulting bio-oils, with a simple upgrading can be an interesting alternative as new biofuels.References: 1Y. Ghasemi, Rasoul-Amini, S., Naseri, A. T., Montazeri-Najafabady, N., Mobasher, M. A., Dabbagh, F., Appl. Biochem.Microbiol. 2012, 48, 126