Preparation, characterization and application of modified surfaces with 3,5-Bis (3,5-dinitrobenzoyl-amino) benzoic acid

JULIETA I. PAEZ; ARIEL L. CAPELLETTI; ANA M. BARUZZI; VERONICA BRUNETTI; MIRIAM C. STRUMIA

MACROMOLECULAR SYMPOSIA

WISLEY

Año: 2010 vol. 290 p. 37 - 45

1022-1360

The spontaneous adsorption of the dendron 3,5-Bis (3,5-dinitrobenzoylamino) benzoic acid (D-NO2) onto gold and carbon electrodes produced conductive surfaces with electroactive chemical functions. A comparative electrochemical behavior of both electrodes after dendron immobilization led us to conclude that the self-assembly of D-NO2 on carbon is faster and stronger. Considering this advantage, the surface of magnetic maghemite nanoparticles (MNPs) was modified using D-NO2. Firstly, MNPs were modified with APS as silane coupling agent and afterwards, D-NO2 was  covalently attached to the surface, achieving nitro-functionalized MNPs. Subsequently, the immobilization of these modified MNPs onto glassy carbon surfaces was explored to generate a novel platform promising for biosensors development.