Facilitated anion transfer reactions across oiljwater interfaces

S.A. DASSIE

JOURNAL OF ELECTROANALYTICAL CHEMISTRY

ELSEVIER

Lugar: Holanda; Año: 2010 vol. 643 p. 20 - 30

0022-0728

In this paper we present the general equations for a model of anion transfer reactions across the oiljwater interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. The equations reported here allow us to simulate the system under a variety of possible conditions. The formation of complex with j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed.jwater interface assisted by a neutral ligand. Our analysis mainly focuses on the effect of water autoprotolysis. The equations reported here allow us to simulate the system under a variety of possible conditions. The formation of complex with j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed.j:k anion-to-ligand stoichiometry is analyzed. Three different models are compared: buffered solutions (BASA model) and unbuffered solutions with and without considering water autoprotolysis (UBASA and UBAS model respectively). Moreover, the analytical relationships for the BASA model between half-wave potential and the initial concentration of anion and ligand are developed.