INFIQC   05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
The development of an environmentally benign sulfide oxidation
Autor/es:
CLAUDIO OMAR KINEN; LAURA ISABEL ROSSI,*; RITA HOYOS DE ROSSI*
Revista:
GREEN CHEMISTRY (PRINT)
Editorial:
Royal Society of Chemistry
Referencias:
Año: 2009 vol. 11 p. 223 - 228
ISSN:
1463-9262
Resumen:
Different Iron (III) species were used as catalysts in sulfoxidation reactions giving excellent yields and high chemoselectivity. Among the iron (III) species, the best one was a solid -cyclodextrin-FeBr3 complex. Sulfoxidation takes place with high chemoselectivity in the presence of other groups such as isothiocyanate. Good results were obtained when these reactions were analyzed using green chemistry metrics.