Different synthetic pathways of nanoparticle-cored dendrimers (NCDs): effects on the properties and their application as redox active centers

JULIETA I. PAEZ; PABLO FROIMOWICZ; KATHERINA LANDFESTER; VERONICA BRUNETTI; MIRIAM C. STRUMIA

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

JOHN WILEY & SONS INC

Año: 2014 vol. 52 p. 3185 - 3197

0887-624X

The synthesis of nanoparticle-cored dendrimers (NCDs) through surface functionalization of iron oxide nanoparticles (γ-Fe2O3) by combining the conventional silane coupling agent 3-(aminopropyl) triethoxysilane (APS) with dendritic moieties is studied and presented. Much emphasis has been put on the role played by each modifier and how they interact not only between themselves, but also with the dispersing media wherein the resulting NCDs are. As a part of the functionalization, redox-active nitro groups were introduced onto the surface of each synthesized NCD thus making them electrochemically active. Then, the obtained NCDs were immobilized onto glassy carbon electrodes. Both the NCDs and modified electrodes are expected to be eventually exploited in analytical and sensing applications. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 3185?3197