INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Stereoselective one-pot synthesis of beta-alkylsulfide enol esters. Base-triggered rearrangement under mild conditions
Autor/es:
ADRIAN HEREDIA; SORIA-CASTRO, SILVIA; BOUCHET, LYDIA; GABRIELA OKSDATH MANSILLA; BARRIONUEVO, ANDREA; CAMINOS, DANIEL; BISOGNO FABRICIO; ARGUELLO, JUAN E; ALICIA BEATRIZ PEÑEÑORY
Revista:
ORGANIC & BIOMOLECULAR CHEMISTRY
Editorial:
ROYAL SOC CHEMISTRY
Referencias:
Lugar: CAMBRIDGE; Año: 2014 vol. 12 p. 6516 - 6526
ISSN:
1477-0520
Resumen:
A stereoselective one-pot procedure was developed to prepare S-substituted (Z)-enol esters through a base-triggered rearrangement. This transition metal-free multicomponent approach can be performed under an air atmosphere at room temperature, tolerates a wide set of chemical functionalities and generally affords high isolated yields. The (Z)-selectivity arises from the [1,4]-S- to O-acyl migration.
