Magnetic properties of the double perovskites LaPbMSbO6 (M = Mn, Co, and Ni)

D. G. FRANCO; R. E. CARBONIO; G. NIEVA

IEEE TRANSACTIONS ON MAGNETICS

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC

Lugar: New York; Año: 2013 vol. 49 p. 4594 - 4597

0018-9464

New double perovskites LaPbMSbO6, where M2+= Mn2+, Co2+, and Ni2+, were synthesized as polycrystals by an aqueous synthetic route at temperatures below 1000o C. All samples are monoclinic, space group P21/n, as it is observed from Rietveld analysis of X-ray powder diffraction patterns. The distribution of M and Sb among the two octahedral sites have 3% of disorder for M2+=Ni2+, whereas for M2+=Mn2+ and Co2+ less disorder is found. The three samples have an antiferromagnetic transition, due to the antiferromagnetic coupling between M through super-superexchange paths M2+-O2--Sb5+-O2--M2+. Transition temperatures are low: 8, 10 and 17 K for Mn2+, Co2+, and Ni2+ respectively, as a consequence of the relatively long distances between the magnetic ions M . Besides, for LaPbMnSbO6 a small transition at 45 K was found, with ferrimagnetic characteristics, possibly as a consequence of a small disorder between Mn2+ and Sb5+. This disorder would give additional and shorter interaction paths: superexchange Mn -O -Mn .