INFIQC   05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
From new simple aliphatic to aromatic heterocycles built from 2-chloroethylisocyanate through proper tuning of reactor´s surface
Autor/es:
PEPINO, ANA JULIETA; PELÁEZ, WALTER J.; ARGUELLO, GUSTAVO A.
Revista:
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
Editorial:
ELSEVIER SCIENCE BV
Referencias:
Lugar: Amsterdam; Año: 2013 vol. 105 p. 49 - 54
ISSN:
0165-2370
Resumen:
New routes for gas phase thermal reactions of 2-chloroethylisocyanate are presented. They can be tuned by simply changing the material of the reactor and the temperature. Many interesting products are formed, including pyrazines and novel imidazolidine-2-ones. A comprehensive analysis that included high level ab-initio calculations has been carried out. Beyond the general agreement found with experimental results, the most relevant information is that, irrespective of the material of the reactor, all the products can be explained through a common unique key intermediate.