INFIQC 05475
INSTITUTO DE INVESTIGACIONES EN FISICO- QUIMICA DE CORDOBA
Unidad Ejecutora - UE
artículos
Título:
Structural Characterization of N-methylcarbamate:beta-cyclodextrin Complexes by Experimental Methods and Molecular Dynamics Simulations
Autor/es:
NATALIA L. PACIONI; ADRIANA B: PIERINI; ALICIA V. VEGLIA
Revista:
SPECTROCHIMICA ACTA. PART A, MOLECULAR AND BIOMOLECULAR SPECTROSCOPY.
Editorial:
PERGAMON-ELSEVIER SCIENCE LTD
Referencias:
Lugar: Amsterdam; Año: 2013 vol. 103 p. 319 - 324
ISSN:
1386-1425
Resumen:
Detailed insights regarding the inclusion process between bcyclodextrin and the N-methylcarbamates insecticides like Bendiocarb, Carbaryl, Carbofuran and Promecarb, is proposed in bases of experimental and computational methods. The results from Fourier Transform Infrared Spectroscopy, Differential Scanning Calorimetry, Induced Circular Dichroism and Molecular Dynamics indicate that only in the case of Promecarb the interaction with the macrocycle is produced by the alkyl rest of the molecule. In all other cases the aromatic moiety is the part of the insecticide that is partially included in the cavity of bcyclodextrin.
Versión on line noviembre 2012
Versión impresa febrero 2013
